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Agriculture Biomass Technology

How pine needles from your used Christmas tree could be turned into a bio-plastic.

How pine needles from your used Christmas tree could be turned into plastic. (Pic from Twitter: @HeatherHintze ) What have you done with your Christmas tree? If its an imitation one, its probably back in the attic, or in the cupboard under the stairs. If its a real one, it is probably like mine languishing somewhat forlornly in your garden awaiting the local council to come and collect it. In the UK alone, theres six to eight million real trees bought a year. And the disposal of them once the festivities are over is a big challenge. Some trees are recycled by being turned into wood chippings, compost or soil conditioner. Though many end up in landfill, which creates an environmental as well as economic cost with the Carbon Trust estimating the carbon footprint of a 2-metre tall tree at 16kg carbon dioxide equivalent due to the methane released as it decomposes. But now scientists at the University of Bath in the UK, have found a potential major use for a by-product from Christmas trees, and have developed a renewable plastic from a chemical called pinene found in pine needles. Pinene is the fragrant chemical from the terpene family that gives pine trees their distinctive Christmas smell and is a waste product from the paper industry. So what exactly has the research found?
Scientists from theCentre for Sustainable Chemical Technologies(CSCT) at the University of Bath hope the plastic could be used in a range of applications, including food packaging, plastic bags and even medical implants.

Degradable polyesters such as PLA (polylactic acid) are made from crops such as corn or sugar cane, but PLA can be mixed with a rubbery polymer called caprolactone to make it more flexible. Caprolactone is made from crude oil, and so the resulting plastic isnt totally renewable.

The researchers publishing their results in the journalPolymer Chemistry, used pinene as the raw material to make a new type of plastic that can be used in the place of caprolactone.

Helena Quilter, PhD student at the CSCT, explained: Were not talking about recycling old Christmas trees into plastics, but rather using a waste product from industry that would otherwise be thrown away, and turning it into something useful. So if we can make a plastic from sustainable sources, it could make a big difference to the environment.

Professor Matthew Davidson, Director of the CSCT and Whorrod Professor of Sustainable Chemical Technologies, added: This research is part of a wider project that looks at using bio-based chemicals like pinene as a sustainable starting material for making a range of useful products, in the place of petrochemicals. This reduces our reliance on fossil fuels and provides a renewable feedstock that has the potential to revolutionise the chemical industry.

The project, funded by the Engineering and Physical Sciences Research Council (EPSRC), is also investigating using other terpenes, such as limonene from citrus fruit, as a substitute for petrochemicals to make a range of products from plastics to pharmaceuticals.

The research is still at the early stages – only a few grams have been made so far – but the scientists aim to scale up the process to produce larger quantities in the near future and their developments could be a part of the creating a more bio-based Christmas.

For more stories about bio-based innovations like this…

The very hungry bacteria; how plastic is on the menu for one microbe.

How orange peel is inspiring a new alternative to plastic packaging.

Australian spinifex grass plus Aboriginal expertise could make condoms ‘as thin as human hair’.

Editor’s focus: Inside the Bioprocess Pilot Facility in Delft.

More plastic than fish in oceans by 2050; report urges circular economy response.

Download now: Bio-Based World Quarterly #4

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